A parallel-plate capacitor containing a polar dielectric with a dielectric constant $k$, connected to a battery with an e.m.f. $E$, is moved from room temperature ($25\text{ }^\circ\text{C}$) into a freezer. What happens to the electrostatic potential energy of the capacitor? (Assume thermal expansion of the plates is neglected and the battery's e.m.f. remains constant.) Answer At room temperature (25 °C), thermal energy causes molecules to vibrate and collide violently and randomly. This thermal chaos fights against the electric field from the battery, constantly knocking the molecular dipoles out of alignment. When capacitor is placed in a cool freezer, the thermal kinetic energy of the molecules drops significantly. With less thermal agitation disrupting them, the electric field becomes much more effective at lining up those molecular dipoles in an orderly fashion. Because more dipoles successfully align with the field, the material's internal polarization increases. A highe...
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